The PokerStars website is available in the United States, but only players in a handful of states can access the real money games listed there. This isn't because PokerStars doesn't want you at the tables. The poker site is active in almost all the US states that have legalized online poker.
The royal flush is a case of the straight flush. It can be formed 4 ways (one for each suit), giving it a probability of 0.000154% and odds of 649,739 : 1.
Two cards, known as hole cards, are dealt face down to each player, and then five community cards are dealt face up in three stages. The stages consist of a series of three cards ("the flop"), later an additional single card ("the turn" or "fourth street"), and a final card ("the river" or "fifth street").